Long-lived quantum-confined infrared transitions in CdSe nanocrystals

D. S. Ginger*, A. S. Dhoot, C. E. Finlayson, N. C. Greenham

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

Crynodeb

We present quasi-steady-state photoinduced absorption measurements on thin films of CdSe nanocrystals dispersed in a polystyrene matrix. For nanocrystals treated with pyridine we observe an intense, size-dependent absorption peaking in the mid-infrared when the samples are irradiated with visible light. This infrared absorption is associated with a size-dependent bleach in the visible, near the peak of the first excitonic absorption. We attribute the infrared absorption to an intraband electron transition in the quantum dots and measure the lifetime of the absorbing state to be 1.0 ms at 295 K.

Iaith wreiddiolSaesneg
Tudalennau (o-i)2816-2818
Nifer y tudalennau3
CyfnodolynApplied Physics Letters
Cyfrol77
Rhif cyhoeddi18
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 30 Hyd 2000

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