Structure and spectroscopy of CuH prepared via borohydride reduction

Elliot L Bennett; Thomas Wilson; Patrick J. Murphy; Keith Refson; Alex C Hannon; Silvia Imberti; Samantha K Callear; Gregory A. Chass; Stewart F. Parker

doi:10.1107/S2052520615015176

Structure and spectroscopy of CuH prepared via borohydride reduction

Elliot L Bennett, Thomas Wilson, Patrick J. Murphy, Keith Refson, Alex C Hannon, Silvia Imberti, Samantha K Callear, Gregory A. Chass, Stewart F. Parker

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Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

10 Dyfyniadau (Scopus)

137 Wedi eu Llwytho i Lawr (Pure)

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Copper(I) hydride (cuprous hydride, CuH) was the first binary metal hydride to be discovered (in 1844) and is singular in that it is synthesized in solution, at ambient temperature. There are several synthetic paths to CuH, one of which involves reduction of an aqueous solution of CuSO4·5H2O by borohydride ions. The product from this procedure has not been extensively characterized. Using a combination of diffraction methods (X-ray and neutron) and inelastic neutron scattering spectroscopy, we show that the CuH from the borohydride route has the same bulk structure as CuH produced by other routes. Our work shows that the product consists of a core of CuH with a shell of water and that this may be largely replaced by ethanol. This offers the possibility of modifying the properties of CuH produced by aqueous routes

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	608-612
Nifer y tudalennau	5
Cyfnodolyn	Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
Cyfrol	71
Rhif cyhoeddi	6
Dyddiad ar-lein cynnar	07 Tach 2015
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1107/S2052520615015176
Statws	Cyhoeddwyd - Rhag 2015

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10.1107/S2052520615015176

Structure and spectroscopy of CuH prepared via borohydride reductionFersiwn derfynol wedi’i chyhoeddi, 686 KB

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http://hdl.handle.net/2160/44036

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@article{e1e81151ba8e4124addf25383efa313f,

title = "Structure and spectroscopy of CuH prepared via borohydride reduction",

abstract = "Copper(I) hydride (cuprous hydride, CuH) was the first binary metal hydride to be discovered (in 1844) and is singular in that it is synthesized in solution, at ambient temperature. There are several synthetic paths to CuH, one of which involves reduction of an aqueous solution of CuSO4·5H2O by borohydride ions. The product from this procedure has not been extensively characterized. Using a combination of diffraction methods (X-ray and neutron) and inelastic neutron scattering spectroscopy, we show that the CuH from the borohydride route has the same bulk structure as CuH produced by other routes. Our work shows that the product consists of a core of CuH with a shell of water and that this may be largely replaced by ethanol. This offers the possibility of modifying the properties of CuH produced by aqueous routes",

keywords = "copper (I) hydride, total scattering neutron diffraction, inelastic neutron scattering spectroscopy, X-ray powder diffraction",

author = "Bennett, {Elliot L} and Thomas Wilson and Murphy, {Patrick J.} and Keith Refson and Hannon, {Alex C} and Silvia Imberti and Callear, {Samantha K} and Chass, {Gregory A.} and Parker, {Stewart F.}",

year = "2015",

month = dec,

doi = "10.1107/S2052520615015176",

language = "English",

volume = "71",

pages = "608--612",

journal = "Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials",

issn = "2052-5192",

publisher = "Wiley",

number = "6",

}

TY - JOUR

T1 - Structure and spectroscopy of CuH prepared via borohydride reduction

AU - Bennett, Elliot L

AU - Wilson, Thomas

AU - Murphy, Patrick J.

AU - Refson, Keith

AU - Hannon, Alex C

AU - Imberti, Silvia

AU - Callear, Samantha K

AU - Chass, Gregory A.

AU - Parker, Stewart F.

PY - 2015/12

Y1 - 2015/12

N2 - Copper(I) hydride (cuprous hydride, CuH) was the first binary metal hydride to be discovered (in 1844) and is singular in that it is synthesized in solution, at ambient temperature. There are several synthetic paths to CuH, one of which involves reduction of an aqueous solution of CuSO4·5H2O by borohydride ions. The product from this procedure has not been extensively characterized. Using a combination of diffraction methods (X-ray and neutron) and inelastic neutron scattering spectroscopy, we show that the CuH from the borohydride route has the same bulk structure as CuH produced by other routes. Our work shows that the product consists of a core of CuH with a shell of water and that this may be largely replaced by ethanol. This offers the possibility of modifying the properties of CuH produced by aqueous routes

AB - Copper(I) hydride (cuprous hydride, CuH) was the first binary metal hydride to be discovered (in 1844) and is singular in that it is synthesized in solution, at ambient temperature. There are several synthetic paths to CuH, one of which involves reduction of an aqueous solution of CuSO4·5H2O by borohydride ions. The product from this procedure has not been extensively characterized. Using a combination of diffraction methods (X-ray and neutron) and inelastic neutron scattering spectroscopy, we show that the CuH from the borohydride route has the same bulk structure as CuH produced by other routes. Our work shows that the product consists of a core of CuH with a shell of water and that this may be largely replaced by ethanol. This offers the possibility of modifying the properties of CuH produced by aqueous routes

KW - copper (I) hydride

KW - total scattering neutron diffraction

KW - inelastic neutron scattering spectroscopy

KW - X-ray powder diffraction

UR - http://hdl.handle.net/2160/44036

U2 - 10.1107/S2052520615015176

DO - 10.1107/S2052520615015176

M3 - Article

C2 - 26634717

SN - 2052-5192

VL - 71

SP - 608

EP - 612

JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

IS - 6

ER -

Structure and spectroscopy of CuH prepared via borohydride reduction

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