TY - JOUR
T1 - Measurement of key compositional parameters in two species of energy grass by Fourier transform infrared spectroscopy
AU - Allison, Gordon Graham
AU - Morris, Catherine
AU - Hodgson, Edward Matthew
AU - Jones, Jenny
AU - Kubacki, Michal
AU - Baraclough, Tim
AU - Yates, Nicola
AU - Shield, Ian
AU - Bridgwater, Anthony V.
AU - Donnison, Iain Simon
N1 - IMPF: 04.25
Sponsorship: BBSRC, EPSRC, EU
RONO: 06339; BBS/E/W/00003134C; BBS/E/W/00003134D
PY - 2009/12
Y1 - 2009/12
N2 - Two energy grass species, switch grass, a North American tuft grass, and reed canary grass, a European native, are likely to be important sources of biomass in Western Europe for the production of biorenewable energy. Matching chemical composition to conversion efficiency is a primary goal for improvement programmes and for determining the quality of biomass feed-stocks prior to use and there is a need for methods which allow cost effective characterisation of chemical composition at high rates of sample through-put. In this paper we demonstrate that nitrogen content and alkali index, parameters greatly influencing thermal conversion efficiency, can be accurately predicted in dried samples of these species grown under a range of agronomic conditions by partial least square regression of Fourier transform infrared spectra (R2 values for plots of predicted vs. measured values of 0.938 and 0.937, respectively). We also discuss the prediction of carbon and ash content in these samples and the application of infrared based predictive methods for the breeding improvement of energy grasses.
AB - Two energy grass species, switch grass, a North American tuft grass, and reed canary grass, a European native, are likely to be important sources of biomass in Western Europe for the production of biorenewable energy. Matching chemical composition to conversion efficiency is a primary goal for improvement programmes and for determining the quality of biomass feed-stocks prior to use and there is a need for methods which allow cost effective characterisation of chemical composition at high rates of sample through-put. In this paper we demonstrate that nitrogen content and alkali index, parameters greatly influencing thermal conversion efficiency, can be accurately predicted in dried samples of these species grown under a range of agronomic conditions by partial least square regression of Fourier transform infrared spectra (R2 values for plots of predicted vs. measured values of 0.938 and 0.937, respectively). We also discuss the prediction of carbon and ash content in these samples and the application of infrared based predictive methods for the breeding improvement of energy grasses.
KW - Ash content
KW - Nitrogen content
KW - Alkali index
KW - Energy grasses
KW - FTIR
U2 - 10.1016/j.biortech.2009.07.015
DO - 10.1016/j.biortech.2009.07.015
M3 - Article
SN - 0960-8524
VL - 100
SP - 6428
EP - 6433
JO - Bioresource Technology
JF - Bioresource Technology
IS - 24
ER -